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Atomic Number: 31
Atomic Symbol: Ga
Atomic Weight: 69.72
Electron Configuration: [Ar]4s23d104p1
History
(L. Gallia, France; also from Latin, gallus, a translation of Lecoq,
a cock) Predicted and described by Mendeleyev as ekaaluminum, and discovered
spectroscopically by Lecoq de Boisbaudran in 1875, who in the same year obtained
the free metal by electrolysis of a solution of the hydroxide in KOH.
Sources
Gallium is often found as a trace element in diaspore, sphalerite,
germanite, bauxite, and coal. Some flue dusts from burning coal have been shown
to contain as much 1.5 percent gallium.
Properties
It is one of four metals -- mercury ,
cesium , and rubidium
-- which can be liquid near room temperature and, thus, can be used in
high-temperature thermometers. It has one of the longest liquid ranges of any
metal and has a low vapor pressure even at high temperatures.
There is a strong tendency for gallium to supercool below its
freezing point. Therefore, seeding may be necessary to initiate solidification.
Ultra-pure gallium has a beautiful, silvery appearance, and the
solid metal exhibits a conchoidal fracture similar to glass. The metal expands
3.1 percent on solidifying; therefore, it should not be stored in glass or metal
containers, because they may break as the metal solidifies.
High-purity gallium is attacked only slowly by mineral acids.
Uses
Gallium wets glass or porcelain and forms a brilliant mirror when it
is painted on glass. It is widely used in doping semiconductors and producing
solid-state devices such as transistors.
Magnesium gallate containing divalent impurities, such as Mn+2,
is finding use in commercial ultraviolet-activated powder phosphors. Gallium
arsenide is capable of converting electricity directly into coherent light.
Gallium readily alloys with most metals, and has been used as a component in
low-melting alloys.
Handling
Its toxicity appears to be of a low order, but should be handled with
care until more data is available.
Sources: CRC Handbook of Chemistry and
Physics and the American Chemical Society.
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